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Butter two 8 inch round cake pans. Line with parchment paper and then butter the paper. Lightly flour both pans and set aside.
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In a stand mixer, briefly combine the flour, sugar, cocoa, baking soda, baking powder, and salt.
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In a separate bowl, whisk together the buttermilk, eggs, oil, and vanilla.
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Add the buttermilk mixture to the dry ingredients and blend until just combined.
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Slowly beat in the hot coffee. Do not overmix.
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Divide the batter into the two prepared pans and bake at 350 degrees for approximately 35 minutes, or until a tester inserted in the middle of the cake comes out clean.
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Allow the cakes to cool for about 30 minutes in the pans and then invert onto cooling racks to finish cooling completely.